The kinetics of dissolution of varnishes: The influence of vapour pressure on the rate of solvent action

Zumbühl, Stefan; Scherrer, Nadim; Engel, N. L.; Mueller, W. (2014). The kinetics of dissolution of varnishes: The influence of vapour pressure on the rate of solvent action In: Bridgland, J. (ed.) ICOM-CC 17th Triennial Conference, 2014 Melbourne, Scientific Research (Art. 1610, 11). Melbourne: International Council of Museums

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Effective and responsible use of solvents is an important competence of a conservator/restorer. The goal to selectively remove components such as varnishes from the surface without affecting underlying paint is a common challenge in the field of restoration. The complexity of the processes of solvation and dissolution has given rise to several approaches by various groups to simplify solvent action and deliver some selection criteria to the restorer. In general, however, these approaches lack both a qualitative and quantitative description of the dissolution processes. In the context of practical conservation needs, knowledge of the rate of solvent action will decide the ability to control a conservation treatment. Since the kinetics of solvent action mainly depend on an entropy change in the dissolving process, a different approach is necessary to satisfy the demands of current conservation practice.

Item Type:

Book Section (Report Section)

Division/Institute:

Bern Academy of the Arts
Bern Academy of the Arts > Institute Materiality in Art and Culture
Bern Academy of the Arts > Institute Materiality in Art and Culture > Material analyses
Bern Academy of the Arts > Institute Materiality in Art and Culture > Teaching material competence in training and further education

Name:

Zumbühl, Stefan0000-0002-8896-2938;
Scherrer, Nadim0000-0002-6576-885X;
Engel, N. L.;
Mueller, W. and
Bridgland, J.

Subjects:

N Fine Arts > ND Painting

ISBN:

978-92-9012-410-8

Publisher:

International Council of Museums

Language:

English

Submitter:

Nadim Scherrer

Date Deposited:

08 Feb 2021 16:04

Last Modified:

20 Apr 2021 14:39

Related URLs:

Additional Information:

Notes: Paris Date: 2014

Uncontrolled Keywords:

dissolution kinetics, dissolution entropy, vapour pressure, cavitation energy, cohesive energy, rate of leaching, varnish materials

ARBOR DOI:

10.24451/arbor.8058

URI:

https://arbor.bfh.ch/id/eprint/8058

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